(4S,5S)-2,2-dimethyl-4-phenyl-1,3-dioxan-5-amine
- Name(4S,5S)-2,2-dimethyl-4-phenyl-1,3-dioxan-5-amine
- CAS35019-66-0
- Purity99%
Product Details
Manufacturer Sells Best Quality (4S,5S)-2,2-dimethyl-4-phenyl-1,3-dioxan-5-amine 35019-66-0 with stock
- Molecular Formula:C12H17 N O2
- Molecular Weight:207.272
- Vapor Pressure:0.000951mmHg at 25°C
- Boiling Point:303.1°Cat760mmHg
- Flash Point:149.5°C
- PSA：44.48000
- Density:1.043g/cm3
- LogP:2.53820
(4S,5S)-2,2-dimethyl-4-phenyl-1,3-dioxan-5-amine(Cas 35019-66-0) Usage
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General Description |
The chemical compound (4S,5S)-2,2-dimethyl-4-phenyl-1,3-dioxan-5-amine is a chiral amine with a bicyclic structure containing a dioxane ring. It is a tertiary amine, meaning that it has three alkyl or aryl substituents attached to the nitrogen atom. The compound is also characterized by its stereochemistry, with the (4S,5S) designation indicating the configuration of its asymmetric carbon atoms. (4S,5S)-2,2-dimethyl-4-phenyl-1,3-dioxan-5-amine may have potential applications in organic synthesis, pharmaceuticals, and materials science due to its unique structure and properties. However, its specific uses and applications would depend on further research and development. |
InChI:InChI=1/C12H17NO2/c1-12(2)14-8-10(13)11(15-12)9-6-4-3-5-7-9/h3-7,10-11H,8,13H2,1-2H3/t10-,11-/m0/s1
35019-66-0 Relevant articles
A chemoenzymatic and fully stereocontrolled total synthesis of the antibacterial natural product (-)-platencin
Chang, Ee Ling,Schwartz, Brett D.,Draffan, Alistair G.,Banwell, Martin G.,Willis, Anthony C.
, p. 427 - 439 (2015/02/05)
The natural product (-)-platencin is a p...
Binaphthalene-derived iminium salt catalysts for highly enantioselective asymmetrie epoxidation
Bulman Page, Philip C.,Buckley, Benjamin R.,Farah, Mohamed M.,John Blacker
experimental part, p. 3413 - 3426 (2011/02/26)
Enantiomerically enriched epoxides are u...
New chiral iminium salt catalysts for asymmetric epoxidation
Bulman Page, Philip C.,Buckley, Benjamin R.,Rassias, Gerasimos A.,Blacker, A. John
, p. 803 - 813 (2007/10/03)
A range of enantiomerically pure 4-subst...
Tandem radical and non-radical reactions mediated with thiols - A new method of cleavage of allylic amines
Bertrand, Michele P.,Escoubet, Stephanie,Gastaldi, Stephane,Timokhin, Vitaliy I.
, p. 216 - 217 (2007/10/03)
Thiyl radical promotes the isomerisation...
35019-66-0 Process route
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-
116-11-0
2-Methoxypropene
-
-
28143-91-1
(1S,2S)-2-amino-1-phenyl-1,3-diol
-
-
35019-66-0
(4S,5S)-2,2-dimethyl-4-phenyl-1,3-dioxan-5-amine
| Conditions | Yield |
|---|---|
|
(1S,2S)-2-amino-1-phenyl-1,3-diol;
With
Methyl formate; sodium methylate;
In
methanol;
at 18 ℃;
for 3.5h;
2-Methoxypropene;
With
toluene-4-sulfonic acid;
In
N,N-dimethyl-formamide;
at 18 ℃;
for 2h;
With
hydrazine hydrate;
In
water;
for 2h;
Reflux;
|
89% |
-
-
102224-22-6
(4S,5S)-5-(formylamino)-2,2-dimethyl-4-phenyl-1,3-dioxane
-
-
35019-66-0
(4S,5S)-2,2-dimethyl-4-phenyl-1,3-dioxan-5-amine
| Conditions | Yield |
|---|---|
|
With
hydrazine hydrate;
In
water;
for 3h;
Reflux;
|
87% |
|
With
hydrazine hydrate;
for 2h;
Heating;
|
79% |
|
With
hydrazine hydrate;
for 2.5h;
Heating;
|
35019-66-0 Upstream products
-
4508-82-1
(+/-)-2,2-dimethyl-4r-phenyl-[1,3]dioxan-5c-ylamine
-
102224-22-6
(4S,5S)-5-(formylamino)-2,2-dimethyl-4-phenyl-1,3-dioxane
-
28143-91-1
(1S,2S)-2-amino-1-phenyl-1,3-diol
-
51317-78-3
(1S,2S)-2-formylamino-1-phenyl-1,3-propanediol
35019-66-0 Downstream products
-
36808-10-3
5-bromo-2,2-dimethyl-4-phenyl-[1,3]dioxane
-
97036-27-6
(2R)-(+)-2-<(4S,5S)-(2,2-Dimethyl-4-phenyl-1,3-dioxan-5-yl)amino>-2-(2-thienyl)acetonitril
-
97036-25-4
(2S)-(+)-2-<(4S,5S)-(2,2-Dimethyl-4-phenyl-1,3-dioxan-5-yl)amino>-2-(2-thienyl)acetonitril
-
97036-23-2
(4S,5S)-(+)-2,2-Dimethyl-4-phenyl-5-<(2-thienylmethylen)amino>-1,3-dioxan
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